Ni catalyst promotion of a Cis-selective Pd catalyst for canola oil hydrogenation

A Ni catalyst was added to a cis-selective Pd catalyst in an attempt to further improve the Pd catalyst's cis-selectivity and activity for canola oil hydrogenation. The system was tested under reaction conditions known to be suitable for cis-selective hydrogenation with the Pd catalyst (50 ppm Pd, 70 °C, and 5.2 MPa). Although inactive on its own under these conditions, the addition of 100 ppm Ni increased the hydrogenation activity (from 2.12 to 2.49 10⁻² min⁻¹). Further addition of Ni up to 1000 ppm resulted in no further improvements in activity. The trans isomer contents of the oils hydrogenated with Pd and the Pd/Ni systems were similar. The level of conjugated dienes decreased rapidly during hydrogenation with both Pd alone and with the Pd/Ni combination and no changes in conjugation were detected in the presence of the Ni catalyst alone. The increased activity of the Pd/Ni system over Pd alone was attributed to adsorption of catalyst poisons from the oil by Ni.     

电子级过氧化氢的质量标准、市场和生产技术

介绍了目前电子级过氧化氢的质量标准;分析了市场状况及其发展趋势;简述了工业生产中常用的几种生产方法.     

Deformation behaviour of iron-doped alumina

Compressive creep tests in air were carried out on 1 cat.% Fe-doped alumina at a temperature T=1400 °C. Iron doping affected the plastic deformation by different ways in relation with Fe²⁺ cations population. Fe²⁺ cations sped up the deformation rates. FeAl₂O₄ spinel precipitates were identified and they were found (i) to interact with alumina grain boundaries (ii) to limit the grain growth within a range of strain. The Fe²⁺ cations underwent oxidation and this resulted in the dissolution of the some precipitates and in the decrease of deformation rates. It was suggested that deformation sped up this evolution through mass transport and that time was not a dominating parameter.     

Electrochemical characteristics of heme proteins in hydroxyethylcellulose film

A stable film made from hydroxyethylcellulose (HEC) on pyrolytic graphite (PG) electrode was employed for incorporating hemoglobin (Hb), myoglobin (Mb) and horseradish peroxidase (HRP), and the electrochemical characteristics of the proteins were studied correspondingly. Experimental results revealed that HEC film could greatly accelerate electron transfer between the proteins and electrode, and the proteins showed a thin layer electrochemical behavior in the film. Moreover, all the proteins in the film exhibited good catalytic activity towards the reduction of hydrogen peroxide (H₂O₂) in the low H₂O₂ concentration range. In the high concentration range, H₂O₂ would exhibit toxicity effect on the proteins. The electrochemical properties and electrocatalytic abilities of the three heme proteins in HEC film have been compared, and the optimal conditions for H₂O₂ biosensor fabrication have been obtained.     

Electrical properties of dysprosium phthalocyanine films

Forty-four nanometers thick films of alkyl-substituted dysprosium phthalocyanine molecules were prepared on carefully cleaned indium tin oxide (ITO) substrates by the spin casting method. UV–vis absorption spectra and dc conduction characteristics were obtained in order to investigate the structure–conduction property relationship. The conduction is Ohmic at low applied voltages but the space charge limited mechanism is prevalent at relatively high voltages. The conductivities of both as-deposited and heat treated films are found to show directionally anisotropic behaviour. The columnar conductivity was found to be significantly large in the liquid crystalline state.     

An updated correlation for crack-arrest fracture toughness for nuclear reactor pressure vessel steels

An updated and statistically-rigorous correlation is provided for crack-arrest toughness values versus normalized temperature for light-water nuclear reactor pressure vessel (RPV) steels. The database used in this effort is larger than applied heretofore and includes results from tests of laboratory-size specimens and from tests of large-scale specimens, which contain features prototypical of operating RPVs. The mathematical methodology used is based on a lognormal distribution, with its parameters calculated by orthogonal distance regression. This correlation was developed as one of several items updated for use in the US Nuclear Regulatory Commission's extensive program to evaluate and potentially revise its rule for ensuring structural integrity of operating RPVs when subjected to pressurized thermal-shock transients.     

Calculations of optical properties in p-doped nitrides quaternary alloys multiple quantum wells

We present theoretical photoluminescence (PL) and absorption spectra of p-doped InGaN/AlInGaN and AlInGaN/InGaN multiple quantum wells (MQWs). The calculations were performed within the k.p method by means of solving a full eight-band Kane Hamiltonian together with the Poisson equation in a plane wave representation, including exchange–correlation effects within the local density approximation. Strain effects due to the lattice mismatch and an internal electric field are also taken into account. We show that by changing the In and Al composition we can reach short and long emission wavelengths. The trends in the calculated Stokes shift, due to many-body effects within the quasi-two-dimensional hole gas (2DHG), are analyzed as a function of the acceptor doping concentration. Since the studies of optical properties of quantum wells based on nitrides quaternary alloys are at an early stage, the results reported here will provide guidelines for the interpretation of forthcoming experiments.     

Photocatalytic evolution of hydrogen over mesoporous TiO2 supported NiO photocatalyst prepared by single-step sol–gel process with surfactant template

Photocatalytic activity of mesoporous titania supported nickel oxide photocatalyst synthesized by single-step sol–gel (SSSG) process combined with surfactant-assisted template method was investigated for hydrogen evolution from an aqueous methanol solution, in comparison with one prepared by conventional incipient wetness impregnation (IWI) method. In single-step sol–gel process, nickel precursor was introduced into the titania sol prepared with the aid of a surfactant template behaving as pore-controlling agent to attain meso-scaled pore. The single-step sol–gel photocatalyst was experimentally found to enhance the photocatalytic evolution of hydrogen rather than the impregnated one. The optimum level of nickel loading in photocatalytic activity test for single-step sol–gel method was slightly higher than that for incipient wetness impregnation method. Characterization results demonstrated the significant modification of physical characteristics of the single-step sol–gel photocatalyst, anticipated to relating to the observation of higher photocatalytic hydrogen evolution activity.